Canadian journal of chemistry

" Through-space" spin-spin coupling between thallium and hydrogen in o-alkylphenylthallium compounds

BV Cheesman, RFM White

Index: Cheesman, Bruce Victor; White, Raymond Frederick Martin Canadian Journal of Chemistry, 1984 , vol. 62, p. 521 - 525

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Citation Number: 9

Abstract

In this study a comparison was made of the sidechain coupling constants for mono-and di- arylthallium derivatives in which a series of alkyl groups (CH3, C2H5, i-C3H7, t-C4H9) are o- and p-to the thallium atom. The results provide evidence of" through-space" coupling between thallium and hydrogen in some of the o-alkylphenylthallium compounds, with the" through-space" contribution to in the o-tert-butylphenylthallium derivatives being ...