e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Synthesis and Characterization of Achiral Bent??Core Liquid Crystalline Molecules Containing Salicylaldimine??Based with a Wide Temperature Range of SmCP Phase

CT Liao, JY Liu, SF Zou, NC Wu…

Index: Liao, Chien-Tung; Liu, Jung-Yo; Zou, Sing-Fang; Wu, Nien-Chieh; Wu, Zheng-Long; Lee, Jiunn-Yih Journal of the Chinese Chemical Society, 2010 , vol. 57, # 1 p. 124 - 133

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Citation Number: 1

Abstract

Abstract The design and synthesis of a series bent-core materials base on a 3, 4′- biphenyldiol central core containing salicylaldimine-based and two terminal tetradecyloxy tails are reported. In addition, the effects of lateral substituents (R= F and Cl) at the biphenyl core into 3′-position are examined. These substituents have a strong influence in reducing the clearing temperatures and increasing temperature range of SmCP phase. Upon ...

1-Bromotetradecane Structure

1-Bromotetradecane

b-Resorcylaldehyde Structure

b-Resorcylaldehyde

~79%

2-hydroxy-4-tetradecoxybenzaldehyde Structure

2-hydroxy-4-tet...

(3'-chlorobiphenyl-3,4'-diyloxy)bis(tetrahydro-2H-pyran) Structure

(3'-chlorobiphe...

~89%

2-chloro-4-(3-hydroxyphenyl)phenol Structure

2-chloro-4-(3-h...

2-(4-bromo-2-chlorophenoxy)tetrahydro-2H-pyran Structure

2-(4-bromo-2-ch...

~%

2-chloro-4-(3-hydroxyphenyl)phenol Structure

2-chloro-4-(3-h...

3-[(2-Tetrahydropyranyl)oxy]phenylboronic Acid Structure

3-[(2-Tetrahydr...

~%

2-chloro-4-(3-hydroxyphenyl)phenol Structure

2-chloro-4-(3-h...

2-(3-Bromophenoxy)tetrahydro-2H-pyran Structure

2-(3-Bromopheno...

~%

2-chloro-4-(3-hydroxyphenyl)phenol Structure

2-chloro-4-(3-h...

3-Bromophenol Structure

~%

2-chloro-4-(3-hydroxyphenyl)phenol Structure

2-chloro-4-(3-h...

4-Bromo-2-chlorophenol Structure

4-Bromo-2-chlor...

~%

2-chloro-4-(3-hydroxyphenyl)phenol Structure

2-chloro-4-(3-h...

3,4-Dihydro-2H-pyran Structure

3,4-Dihydro-2H-pyran

3-Bromophenol Structure

~88%

2-(3-Bromophenoxy)tetrahydro-2H-pyran Structure

2-(3-Bromopheno...

3,4-Dihydro-2H-pyran Structure

3,4-Dihydro-2H-pyran

4-Bromo-2-fluorophenol Structure

4-Bromo-2-fluor...

~84%

2-(4-bromo-2-fluorophenoxy)oxane Structure

2-(4-bromo-2-fl...

2-(3-Bromophenoxy)tetrahydro-2H-pyran Structure

2-(3-Bromopheno...

~65%

3-[(2-Tetrahydropyranyl)oxy]phenylboronic Acid Structure

3-[(2-Tetrahydr...

N/A Structure

~80%

2-fluoro-4-(3-hydroxyphenyl)phenol Structure

2-fluoro-4-(3-h...

2-(4-bromo-2-fluorophenoxy)oxane Structure

2-(4-bromo-2-fl...

~%

2-fluoro-4-(3-hydroxyphenyl)phenol Structure

2-fluoro-4-(3-h...

3-[(2-Tetrahydropyranyl)oxy]phenylboronic Acid Structure

3-[(2-Tetrahydr...

~%

2-fluoro-4-(3-hydroxyphenyl)phenol Structure

2-fluoro-4-(3-h...

2-(3-Bromophenoxy)tetrahydro-2H-pyran Structure

2-(3-Bromopheno...

~%

2-fluoro-4-(3-hydroxyphenyl)phenol Structure

2-fluoro-4-(3-h...

3-Bromophenol Structure

~%

2-fluoro-4-(3-hydroxyphenyl)phenol Structure

2-fluoro-4-(3-h...

4-Bromo-2-fluorophenol Structure

4-Bromo-2-fluor...

~%

2-fluoro-4-(3-hydroxyphenyl)phenol Structure

2-fluoro-4-(3-h...

N/A Structure

~91%

[1,1'-biphenyl]-3,4'-diol Structure

[1,1'-biphenyl]...

2-(4-Bromophenoxy)tetrahydro-2H-pyran Structure

2-(4-Bromopheno...

~%

[1,1'-biphenyl]-3,4'-diol Structure

[1,1'-biphenyl]...