Cycloalkylmethyl radicals. Part 7.—Electron paramagnetic resonance characterisation of axial and equatorial centres in seven-membered alicyclic molecules

AC Hindson, JC Walton

Index: Hindson, Andrew C.; Walton, John C. Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 19 p. 3237 - 3241

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Citation Number: 8

Abstract

The EPR spectra of cycloheptylmethyl, cyclohept-4-enylmethyl and 1, 3-dioxacyclohept-5- enylmethyl radicals have been observed. The cycloheptylmethyl radical spectrum shows only a single, average conformation, but for the cycloheptene and dioxacycloheptene rings the CH group proved to be a useful probe of the conform