Photoequilibration of 2-naphthylcarbene and 2, 3-benzobicyclo [4.1. 0] hepta-2, 4, 6-triene

SW Albrecht, RJ McMahon

Index: Albrecht, Steven W.; McMahon, Robert J. Journal of the American Chemical Society, 1993 , vol. 115, # 3 p. 855 - 859

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Citation Number: 29

Abstract

Abstract: Irradiation (A> 300 nm or A= 480 f 6 nm) of 2-naphthyldiazomethane (4), matrix- isolated in argon at 10 K, gives a mixture of 2-naphthylcarbene (1) and 2, 3-benzobicycl0 [4.1. O] hepta-2, 4, 6-triene (2). 2-Naphthylcarbene (1) is characterized by infrared, UV/visible, and ESR spectroscopy and by chemical trapping with CO. 2, 3-Benzobicyclo [4.1. O] hepta-2, 4, 6-triene (2) is characterized by infrared and UV/visible spectroscopy. A ...