Microwave-assisted dry oxidation of 3-trialkylsilyl (germyl) prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes

AV Mareev, AS Medvedeva, AV Khatashkeev…

Index: Mareev, Alexander V.; Medvedeva, Alevtina S.; Khatashkeev, Alexander V.; Afonin, Andrey V. Mendeleev Communications, 2005 , # 6 p. 263 - 265

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Citation Number: 10

Abstract

The efficient solvent-free microwave-assisted oxidation of 3-trialkylsilyl (germyl) prop-2-yn-1- ols with manganese dioxide or pyridinium chlorochromate to propynals and the direct conversion of acetylenic alcohols to the corresponding imines and Knövenagel adducts have been carried out.