Tetrahedron

Electroreduction in aqueous media, saturation of polycyclic aromatics

E Kariv-Miller, RI Pacut

Index: Kariv-Miller, Essie; Pacut, Ryszard I. Tetrahedron, 1986 , vol. 42, # 8 p. 2185 - 2192

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Citation Number: 11

Abstract

The preparative cathodic reduction of anthracene and phenanthrene was investigated aiming at obtaining Birch-type products in aqueous solutions. Following previous reports, reductions were carried out using mercury pool cathodes and tetrabutylammonium electrolytes. Optimum conditions were found to involve tetrabutylammonium hydroxide as the electrolyte and water as the sole solvent. Reactions were carried out in a simple cell, ...

 Related Synthetic Route
Anthracene Structure

120-12-7

Anthracene

~1%

Anthracene,9,10-dihydro- Structure

613-31-0

Anthracene,9,10...

1,2,3,4,5,6,7,8,9,10-decahydroanthracene Structure

3485-60-7

1,2,3,4,5,6,7,8...

1,4,5,8,9,10-Hexahydroanthracene Structure

5910-28-1

1,4,5,8,9,10-He...

Detail
Anthracene Structure

120-12-7

Anthracene

~%

1,2,3,4,5,6,7,8,9,10-decahydroanthracene Structure

3485-60-7

1,2,3,4,5,6,7,8...

1,4,5,8,9,10-Hexahydroanthracene Structure

5910-28-1

1,4,5,8,9,10-He...

Anthracene,1,2,3,4,5,6,7,8-octahydro- Structure

1079-71-6

Anthracene,1,2,...

Detail
Anthracene Structure

120-12-7

Anthracene

~%

Anthracene,9,10-dihydro- Structure

613-31-0

Anthracene,9,10...

1,2,3,4,5,6,7,8,9,10-decahydroanthracene Structure

3485-60-7

1,2,3,4,5,6,7,8...

1,4,5,8,9,10-Hexahydroanthracene Structure

5910-28-1

1,4,5,8,9,10-He...

Detail
Anthracene Structure

120-12-7

Anthracene

~%

1,4,5,8,9,10-Hexahydroanthracene Structure

5910-28-1

1,4,5,8,9,10-He...

Anthracene,1,2,3,4,5,6,7,8-octahydro- Structure

1079-71-6

Anthracene,1,2,...

1,2,3,4,5,6-hexahydroanthracene Structure

6109-22-4

1,2,3,4,5,6-hex...

Anthracene Structure

120-12-7

Anthracene

~%

1,2,3,4,5,6,7,8,9,10-decahydroanthracene Structure

3485-60-7

1,2,3,4,5,6,7,8...

1,4,5,8,9,10-Hexahydroanthracene Structure

5910-28-1

1,4,5,8,9,10-He...

Anthracene,1,2,3,4,5,6,7,8-octahydro- Structure

1079-71-6

Anthracene,1,2,...

Detail
Anthracene Structure

120-12-7

Anthracene

~%

Anthracene,9,10-dihydro- Structure

613-31-0

Anthracene,9,10...

1,2,3,4,5,6,7,8,9,10-decahydroanthracene Structure

3485-60-7

1,2,3,4,5,6,7,8...

1,4,5,8,9,10-Hexahydroanthracene Structure

5910-28-1

1,4,5,8,9,10-He...

Detail

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