European journal of organic chemistry

Ligand??Free Iron/Copper??Cocatalyzed Amination of Aryl Iodides

XF Wu, C Darcel

Index: Wu, Xiao-Feng; Darcel, Christophe European Journal of Organic Chemistry, 2009 , # 28 p. 4753 - 4756

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Citation Number: 35

Abstract

Abstract The Fe 2 O 3/CuI system efficiently catalyzes the direct amination of aryl iodides with aqueous ammonia in ethanol at 90 C under aerobic conditions. No ligand was used to perform such reaction. A very wide variety of functional groups was tolerated on the aryl iodide partner. This procedure is economically and environmentally attractive as a result of the use of aqueous ammonia and ethanol.(© Wiley-VCH Verlag GmbH & Co. KGaA, ...