Synthesis of methylenecyclopropene

WE Billups, LJ Lin, EW Casserly

Index: Billups,W.E.; Lin,L.J.; Casserly,E.W. Journal of the American Chemical Society, 1984 , vol. 106, p. 3698

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Citation Number: 77

Abstract

I considerable research effort.'Physical evidence for the parent hydrocarbon is, however, completely lacking despite the intense theoretical interest in this molecule. 2 We now wish to report the synthesis and characterization of this compound. The starting material z3 was prepared from allene and chlorocarbene (CH2C12, CH3Li). 4 The bromide 3 is an equally

~40%

Electronic character of methylenecyclopropene: microwave spe...

[Norden, Timothy D.; Staley, Stuart W.; Taylor, William H.; Harmony, Marlin D. Journal of the American Chemical Society, 1986 , vol. 108, # 25 p. 7912 - 7918]

Neue wege zum cyclobutadien und methylencyclopropen

[Maier, Guenther; Hoppe, Manfred; Lanz, Klaus; Reisenauer, Hans Peter Tetrahedron Letters, 1984 , vol. 25, # 49 p. 5645 - 5648]

A flow tube study of ion-molecule reactions of acetylene

[Knight, J. S.; Freeman, C. G.; McEwan, M. J.; Anicich, V. G.; Huntress, W. T. Journal of Physical Chemistry, 1987 , vol. 91, # 14 p. 3898 - 3902]