Clocking Tertiary Cyclopropylcarbinyl Radical Rearrangements1

PS Engel, SL He, JT Banks, KU Ingold…

Index: Duismann,W. et al. Tetrahedron Letters, 1974 , p. 265 - 268

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Citation Number: 26

Abstract

... rearranged radicals. 12 With the assumption that Franz et al.'s 13 LFP measured rate constant for the tert-butyl/thiophenol reaction, , is equal to values of and were calculated to be 1.5 × 10 7 s - 1 and 1.1 × 10 7 s - 1 , respectively. 12 ...