Tetrahedron

Total synthesis of the polyene macrolide dermostatin A

CJ Sinz, SD Rychnovsky

Index: Tetrahedron, , vol. 58, # 32 p. 6561 - 6576

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Citation Number: 29

Abstract

... Tetrahedron. Volume 58, Issue 32, 5 August 2002, Pages 6561–6576. ... Conversion of 31 to methyl ketone 32, and subsequent treatment with LDA/TMSCl provided enol silane 33 (Scheme 5). Notably, none of the product arising from 5-exo-tetO-alkylation was observed. ...