抄録: A lithium hydroxide promoted simple glycosylation of 4-hydroxyindole-3-acetonitrile with 2, 3, 4, 6-tetra-O-acetyl-aD-glucopyranosyl bromide was developed. Utilizing the method, the first and five steps total synthesis of cappariloside A was achieved from indole-3- carbaldehyde in 41% overall yield.
