Reactions of tert-butyl tetraethylphosphorodiamidite with acetic and trifluoroacetic acids

LK Sal'keeva, MT Nurmagambetova…

Index: Sal'keeva; Nurmagambetova; Kurmanaliev; Gazizov Russian Journal of General Chemistry, 2003 , vol. 73, # 2 p. 183 - 186

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Citation Number: 5

Abstract

Abstract Reactions of tert-butyl tetraethylphosphorodiamidite with acetic and trifluoroacetic acids involve substitution of the amido group. This process was described by a scheme beginning with protonation of phosphorus and proved by modeling separate reaction stages. A probable scheme of the proposed reactions is described.