Inorganic Chemistry

Synthesis and Moessbauer and vibrational spectra of some new tin (IV)-fluorine compounds

LE Levchuk, JR Sams, F Aubke

Index: Levchuk, L. E.; Sams, J. R.; Aubke, F. Inorganic Chemistry, 1972 , vol. 11, p. 43 - 50

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Citation Number: 53

Abstract

The study by Ruff and Plato7 had indicated that anhydrous HF is a mild fluorinating agent, capable of cleaving the tin-chlorine bond under mild conditions. This suggested that HF might be also employed in the fluorination of methyltin (1V) chlorides. Neither organotin (1V) trifluorides nor mixed organotin (1V) fluoride chlorides have been synthesized and characterized to date. That this deficiency in an otherwise well-represented group of ...