Syntheses a partir de carbanions allyliques silicies: II. Methode selective de metallation

RJP Corriu, GF Lanneau, JP Masse…

Index: Corriu,R.J.P. et al. Journal of Organometallic Chemistry, 1977 , vol. 127, p. 281 - 288

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Citation Number: 11

Abstract

Abstract Diphenylallylvinylsilane undergoes selective addition of n-butyllithium/TMEDA complex on the α-silyl double bond, while methyllithium/TMEDA affords the metallation of the allylic group, without modification of the vinyl group. From our results, metallation appeared highly selective. There is no formation of the dianion. These α-silylcarbanions are good precursors to linear or substituted silylalcohols.