Tetrahedron Letters

Rearrangements of N-acyl-2-aza-1, 5-hexadienes: application to synthesis of traechelanthamidine and supinidine

DJ Hart, TK Yang

Index: Hart, David J.; Yang, Teng-Kuei Tetrahedron Letters, 1982 , vol. 23, # 27 p. 2761 - 2764

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Citation Number: 28

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Efficient syntheses of the pyrrolizidine bases traechelanthamide ( ) and supinidine ( ) via an N-acyliminium ion rearrangement-cyclization are described. ... 2-azonia [3,3] sigmatropic rearrangements reported by Overman. For examples see: J. Am. Chem. Soc., 103 (1981), p. 5579 and ...