Cross-metathesis of divinylsubstituted silanes and disiloxanes in the presence of Grubbs catalysts

C Pietraszuk, S Rogalski, M Majchrzak…

Index: Pietraszuk, Cezary; Rogalski, Szymon; Majchrzak, Mariusz; Marciniec, Bogdan Journal of Organometallic Chemistry, 2006 , vol. 691, # 24-25 p. 5476 - 5481

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Citation Number: 11

Abstract

Efficient cross-metathesis of divinylsilanes and divinyldisiloxanes, carrying different electron- withdrawing substituents at silicon, with selected olefins in the presence of the first and second generation Grubbs catalyst and Hoveyda–Grubbs catalyst is described. The reaction was proved to be a valuable method for synthesis of unsaturated organosilicon derivatives and a model for the study of synthesis of oligo-and polymeric products via ADMET ...