Journal of Organometallic Chemistry

Chemistry of organosilicon compounds: CXXIII. New photochemical and thermal degradation reactions of vinyldisilanes to vinylsilanes through (η3-1-silapropenyl) …

H Sakurai, Y Kamiya, Y Nakadaira

Index: Sakurai, Hideki; Kamiyama, Yoshiyasu; Nakadaira, Yasuhiro Journal of Organometallic Chemistry, 1980 , vol. 184, # 1 p. 13 - 30

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Citation Number: 17

Abstract

Abstract Vinyldisilanes (II) of the type R 1 CH CR 2 SiMe 2 SiMe 3 (a, R 1 Ph, R 2 H; b, R 1 H, R 2 Me; c, R 1 R 2 H) and (R 1 CH CHSiMeR 3−) 2 (d, R 1 Ph, R 3 Me; e, R 1 H, R 3 Ph) undergo a novel degradation reaction to give the corresponding vinylsilanes, R 1 CH CR 2 SiMe 3 and (R 1 CH CH) 2 SiMeR 3, respectively, under photochemical or thermal conditions in the presence of a stoichiometric amount of ...