Perchlorocoronene: a novel host precursor

T Baird, JH Gall, DD MacNicol, PR Mallinson…

Index: Baird, Thomas; Gall, James H.; MacNicol, David D.; Mallinson, Paul R.; Michie, C. Ronald Journal of the Chemical Society, Chemical Communications, 1988 , # 22 p. 1471 - 1473

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Citation Number: 16

Abstract

The title compound (1b), a new non-planar chlorocarbon possessing approximate D3d symmetry, has been prepared by chlorination of coronene (1a); complete substitution of (1b) by arenethiolate nucleophiles in the dipolar aprotic solvent DMEU (1, 3-dimethylimidazolidin- 2-one) yields the dodecathioethers (2a) and (2b), members of a new prospective host series.