The influence of the magnetic field as a tool for investigation of the mechanism of reations of triethylgermyl radicals

MB Taraban, TV Leshina, KM Salikhov…

Index: Taraban, M. B.; Leshina, T. V.; Salikhov, K. M.; Sagdeev, R. Z.; Molin, Yu. N.; et al. Journal of Organometallic Chemistry, 1983 , vol. 256, # 1 p. 31 - 36

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Citation Number: 12

Abstract

Abstract The influence of the external magnetic field on the product yield in the reaction of Et 3 GeM (where M= Na, K) withy benzyl chloride was investigated. A mechanism for magnetic effects in this reaction is proposed. To verify the mechanism proposed, theoretical calculations of the recombination probability of triethylgermyl and benzyl singlet radical pairs were carried out. It is proposed that associated state of the organometallic compound in ...