Journal of the American Chemical Society

Photochemical Reactions of 1, 2-Diketones

WH Urry, DJ Trecker

Index: Urry,W.H.; Trecker,D.J. Journal of the American Chemical Society, 1962 , vol. 84, p. 118 - 120

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Citation Number: 58

Abstract

Sir: n-Bonded metal complexes of the cyclic moieties C, H, are known for n= 4, 5, 6, 7 and 8. We attempted to prepare a complex containing a cyclopropenyl ligand n-bonded to a metal. Orgel'has mentioned the possibility of such complexes and noted the molecular orbitals involved. In practice, we have sought a complex of triphenylcyclopropenyl since triphenylcyclopropenyl bromide is synthesized readily2 and is highly symmetrical. ...

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