Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis (1, 3-diketonato) cobalt (II) complexes.

…, T Yamada, T Takai, S Inoki, S Isayama

Index: Kato; Yamada; Takai; Inoki; Isayama Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 1 p. 179 - 186

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Citation Number: 81

Abstract

In the presence of a bis (1, 3-diketonato) cobalt (II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol (“oxidation–reduction hydration”). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt (II) catalyst as bis ( ...