Remarkable Lewis acid catalytic performance of the scandium trimesate metal organic framework MIL-100 (Sc) for C–C and C [double bond, length as m-dash] N …

L Mitchell, B Gonzalez-Santiago, JPS Mowat…

Index: Mitchell, Laura; Gonzalez-Santiago, Berenice; Mowat, John P. S.; Gunn, Mary E.; Williamson, Patrick; Acerbi, Nadia; Clarke, Matthew L.; Wright, Paul A. Catalysis Science and Technology, 2013 , vol. 3, # 3 p. 606 - 617

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Citation Number: 50

Abstract

The porous metal organic frameworks scandium trimesate MIL-100(Sc), scandium terephthalates MIL-101(Sc), MIL-88B(Sc) and MIL-68(Sc), scandium 4,4′-biphenyl-dicarboxylate MIL-88D(Sc) and the scandium 3,3′,5,5-azobenzene-tetracarboxylate socMOF(Sc) have been compared as Lewis acid catalysts against Sc 3+ -exchanged zeolite Beta, MIL-100(Cr), MIL-101(Cr), MIL-100(Fe) and the divalent MOFs HKUST-1(Cu), CPO-27(Ni) and ...