Four-coordinate Pd (II) complexes containing non-symmetric phosphorus ylides: Synthesis, characterization, and catalytic behavior towards Suzuki reaction

…, M Panahimehr, M Ahmadi, Z Nasri, HR Khavasi

Index: Sabounchei, Seyyed Javad; Panahimehr, Mohammad; Ahmadi, Mohsen; Nasri, Zahra; Khavasi, Hamid Reza Journal of Organometallic Chemistry, 2013 , vol. 723, p. 207 - 213

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Citation Number: 22

Abstract

In this paper it is reported the synthesis of the complexes of the type {[Ph2PCH2PPh2CHC (O) R] PdCl2}(R= 4′-biphenyl (1), OCH2Ph (2), 4-methylphenyl (3), 2-naphtyl (4), 2, 4- dichlorophenyl (5), 3-nitrophenyl (6)) derived from the reactions of the dichloro (1, 5- cyclooctadiene) palladium (II) with related phosphorus ylides in dichloromethane under mild conditions. These compound have been characterized by, elemental analysis and ...