Role of defects in radiation chemistry of crystalline organic materials. 3. Geometrical and electronic structures of alkene radical anion and cation in alkene/n-alkane …

K Matsuura, H Muto, K Nunome

Index: Matsuura, Kaoru; Muto, Hachizo; Nunome, Keichi Journal of Physical Chemistry, 1991 , vol. 95, # 23 p. 9481 - 9487

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Citation Number: 2

Abstract

Results 4 K Irradiation of t”-3-Hexene/n-Hexane. Figure la shows the first-derivative absorption ESR spectrum obtained for the trans-3-hexene (4.0 mol%)/n-C6D14 mixed crystals irradiated at 4.2 K. Figure lb is the spectrum measured after the sample was illuminated with infrared light (for 5 s by a 60-W tungsten lamp using a VR69 filter (Toshiba Co. Ltd.) from a distance of 10 cm). It was the same spectrum as that obtained for the pure ...