Tetrahedron

The thermally induced synthesis of N-(diethoxyphosphoryl) aldimines

A Zwierzak, A Napieraj

Index: Zwierzak, Andrzej; Napieraj, Anna Tetrahedron, 1996 , vol. 52, # 26 p. 8789 - 8794

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Citation Number: 23

Abstract

The reaction of diethyl phosphoroamidate (2) with aromatic aldehyde diethyl acetals (1) carried out at 120–160° C provides a simple, one-step preparation of N- (diethoxyphosphoryl) aldimines (3a− b). The extension of this reaction to aliphatic aldehyde diethyl acetals failed to give the expected imines.