Organometallics

Reaction of mono-and dilithioferrocene with octachlorocyclotetraphosphazene. The crystal and molecular structures of N4P4Cl6 [(n-C5H4) Fe (. eta.-C5H5)] 2 and …

HR Allcock, KD Lavin, GH Riding, RR Whittle

Index: Allcock, Harry R.; Lavin, Karen D.; Riding, Geoffrey H.; Whittle, Robert R. Organometallics, 1984 , vol. 3, p. 663 - 669

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Citation Number: 21

Abstract

New and unusual derivatives of cyclophosphazenes bearing ferrocene substituents have been synthesized by the reactions of mono-and dilithioferrocene with odachlorocyclotetraphosphazene,(NPC12) 4, and with equimolar mixtures of hexachlorocyclotriphosphazene,(NPC1JS, and (NPC12),. The reactions of monolithioferrocene with (NPCLJ4 gave N4P4C& [(+ 25H4) Fe (q-CsH6)] 2 (4) in which ...