New synthetic approach to phenylmethanesulfonamide derivatives on the basis of phenyl-N-(2, 2, 2-trichloroethylidene)-methanesulfonamide

YA Aizina, GG Levkovskaya, IB Rozentsveig

Index: Aizina; Levkovskaya; Rozentsveig Russian Journal of Organic Chemistry, 2012 , vol. 48, # 4 p. 477 - 480

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Abstract

Abstract The reaction of N, N-dichlorophenylmethanesulfonamide with trichloroethylene gave a new representative of highly electrophilic N-sulfonyl-substituted polyhalogenated aldehyde imines, phenyl-N-(2, 2, 2-trichloroethylidene) methanesulfonamide. High reactivity of the product was demonstrated by alkylation of toluene, anisole, thiophene, and 2- chlorothiophene.