Tetrahedron

Azabrendanes IV. Synthesis and characterization of N-(alkyl-and benzylsulfonyl)-exo-2-hydroxy-4-azatricyclo [4.2. 1.0 3, 7] nonanes

LI Kasyan, IN Tarabara, AO Kasyan, SI Okovytyy…

Index: Kasyan, Lilija I.; Tarabara, Igor N.; Kasyan, Andrey O.; Okovytyy, Sergiy I.; Tokar, Andrey V.; Shishkina, Svetlana V.; Shishkin, Oleg V. Tetrahedron, 2007 , vol. 63, # 8 p. 1790 - 1797

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Citation Number: 15

Abstract

exo-and endo-5-Aminomethylbicyclo [2.2. 1] hept-2-enes have been obtained from stereoisomeric exo-and endo-5-cyanobicyclo [2.2. 1] hept-2-enes and the corresponding sulfonamides were obtained through reaction of amines with methyl-, n-propyl-, n-butyl-, benzyl-, and cyclohexylsulfonyl chlorides. From the stereoisomeric sulfonamides with peroxy acids, various products were obtained: exo-sulfonamides were transformed into epoxy ...