Journal of Chemical Crystallography

Synthesis, crystal structure and spectroscopic properties of an oximato bridged cu (II) dimer

JP Naskar, C Biswas, L Lu, M Zhu

Index: Naskar, Jnan Prakash; Biswas, Chiranjan; Lu, Liping; Zhu, Miaoli Journal of Chemical Crystallography, 2011 , vol. 41, # 4 p. 502 - 507

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Citation Number: 10

Abstract

Abstract Schiff-base condensation of a equimolar proportion of diacetyl-monoxime monohydrazone and 1-methylimidazole-2-carboxaldehyde in methanol gives rise to the imidazole azine, 3-(1-methylimidazol-2-yl) methylenehydrazonobutan-2-one oxime (HL). Reaction of 1: 1 stoichiometric proportion of HL with copper (II) perchlorate hexahydrate in methanol yields a dimeric oximato bridged copper compound,[Cu 2 L 2 (H 2 O) 2](ClO 4) 2 ...