Sulfonamidoquinoline/Palladium (II)??Dimer Complex As a Catalyst Precursor for Palladium??Catalyzed γ??Selective and Stereospecific Allyl–Aryl Coupling Reaction …

…, H Ohmiya, M Sawamura

Index: Makida, Yusuke; Ohmiya, Hirohisa; Sawamura, Masaya Chemistry - An Asian Journal, 2011 , vol. 6, # 2 p. 410 - 414

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Citation Number: 29

Abstract

Transition-metal-catalyzed allylic substitution reactions with carbon nucleophiles are powerful carbonÀcarbon bondformation methods because of their broad substrate scope under mild reaction conditions. For example, Tsuji–Trost allylic substitution involving a (p- allyl) metal intermediate has made impressive progress in this regard.[1] However, the allylic substitution of unsymmetrically substituted allylic substrates occurs competitively at the a- ...