Polynuclear aryl derivatives of Group 11 metals. Synthesis, solid state-solution structural relationship, and reactivity with phosphines

…, S Gambarotta, C Floriani, A Chiesi-Villa…

Index: Meyer, Edouard Marc; Gambarotta, Sandro; Floriani, Carlo; Chiesi-Villa, Angiola; Guastini, Carlo Organometallics, 1989 , vol. 8, p. 1067 - 1079

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Citation Number: 194

Abstract

4, Ddcd= 1.232 g~ m-~. The final R factor was 0.10 for 1629 observed reflections. Complex 2: space group R3 (rhombohedral), a= b= c= 18.395 (3) A, a= p= y= 116.28 (2)', V= 3038 (4) A3, Z= 3, Dcdcd= 1.489 g~ m-~. The final R factor was 0.062 (R,= 0.064) for 1966 observed reflections. Complex 3: space group Pnma (orthorhombic), a= 21.864 (10) A, b= 27.188 (11) A, c= 8.951 (5) A, V= 5321 (4) A3, Z= 4, Ddcd= 2.153 g~ m-~. The final R factor was 0.052 ...