Evaluation of Aromatic Amination Catalyzed by Palladium on Carbon: A Practical Synthesis of Triarylamines

Y Monguchi, K Kitamoto, T Ikawa…

Index: Advanced Synthesis and Catalysis, , vol. 350, # 17 p. 2767 - 2777

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Citation Number: 40

Abstract

... phenylmorpholine, whereas the bulkier and stiffer bidentate phosphine ligands efficiently activat- ed the catalysis (entries 16 ... aryl bromides or aryl chlorides using Pd/C as a catalyst to synthesize di- and ... General Procedure for Triarylamine Synthesis from Diphenylamine (Table 7 ...

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Bromobenzene Structure

108-86-1

Bromobenzene

3-anisidine Structure

536-90-3

3-anisidine

~24%

N-Phenyl-m-anisidine Structure

101-16-6

N-Phenyl-m-anisidine

3-methoxy-N,N-diphenylaniline Structure

20588-62-9

3-methoxy-N,N-d...

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Structure

74497-02-2

4-Chlorobiphenyl Structure

2051-62-9

4-Chlorobiphenyl

~39%

N-Phenyl-4-biphenylamine Structure

32228-99-2

N-Phenyl-4-biph...

N-(4-Biphenylyl)-N-phenyl-4-biphenylamine Structure

122215-84-3

N-(4-Biphenylyl...

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4-Bromobiphenyl Structure

92-66-0

4-Bromobiphenyl

Structure

74497-02-2

~23%

N-Phenyl-4-biphenylamine Structure

32228-99-2

N-Phenyl-4-biph...

N-(4-Biphenylyl)-N-phenyl-4-biphenylamine Structure

122215-84-3

N-(4-Biphenylyl...

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3,4-Dimethylbromobenzene Structure

583-71-1

3,4-Dimethylbro...

Structure

74497-02-2

~58%

N,N'-Bis(3,4-dimethylphenyl) aniline Structure

165320-08-1

N,N'-Bis(3,4-di...

3,4-Dimethyl-N-phenylaniline Structure

17802-36-7

3,4-Dimethyl-N-...

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2-Bromopyridine Structure

109-04-6

2-Bromopyridine

Structure

74497-02-2

~38%

N-phenyl-N-pyridin-2-ylpyridin-2-amine Structure

14192-97-3

N-phenyl-N-pyri...

2-Anilinopyridine Structure

6631-37-4

2-Anilinopyridine

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4,4'-Dibromobiphenyl Structure

92-86-4

4,4'-Dibromobiphenyl

Diphenylamine Structure

122-39-4

Diphenylamine

~73%

N,N,N',N'-Tetraphenylbenzidine Structure

15546-43-7

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