Synthesis and spectral data of some new N-nitroso-N-phenylhydroxylamine (cupferron) derivatives

AT Balaban, RE Garfield, MJ Lesko…

Index: Balaban, Alexandru T.; Garfield, Robert E.; Lesko, Melanie J.; Seitz, William A. Organic Preparations and Procedures International, 1998 , vol. 30, # 4 p. 439 - 446

Full Text: HTML

Citation Number: 34

Abstract

5. Reaction of aryl Grignard reagents with two equivalents of NO. I4 6. Reaction of hyponitrous acid salts with nitroarenes or nitrosoarenes. lS Very few theoretical studies on cupferron analogs are available. I6 The preparation of N-phenylhydroxylamine by reduction of nitrobenzene with zinc, and its nitrosation with alkyl nitrites in the presence of gaseous ammonia leading to cupferron is described in salts in the presence of Cu (II) and Fe (II) ...