Triplet states mediating hydrogen abstraction in 4-acylpyrimidines, 2-acylpyridines, 2-acylpyrazines, and 3-acylpyridazines

S Prathapan, KE Robinson…

Index: Journal of the American Chemical Society, , vol. 114, # 5 p. 1838 - 1843

Full Text: HTML

Citation Number: 19

Abstract

... 0 1992 American Chemical Society Page 2. ... These results led us to focus attention on the possibility that in 4-acylpyrimidines a single triplet mediates ... with the concomitant formation of acetophenone from type I1 elimination of val- erophenone as a chemical actinometer: Wagner ...

 Related Synthetic Route
Pyrazinecarbonitrile Structure

19847-12-2

Pyrazinecarbonitrile

~%

1-(1,4-Dihydro-2-pyrazinyl)ethanone Structure

22047-25-2

1-(1,4-Dihydro-...

1-Butanone,1-(2-pyrazinyl)- Structure

61892-81-7

1-Butanone,1-(2...

~1%

1-(1,4-Dihydro-2-pyrazinyl)ethanone Structure

22047-25-2

1-(1,4-Dihydro-...

N/A Structure

138836-01-8

N/A

3-methyl-1-pyrazin-2-ylbutan-1-one Structure

86461-64-5

3-methyl-1-pyra...

~1%

1-(1,4-Dihydro-2-pyrazinyl)ethanone Structure

22047-25-2

1-(1,4-Dihydro-...

2,2-dimethyl-1-(pyrazin-2-yl)cyclopropanol Structure

138836-03-0

2,2-dimethyl-1-...

1-(PYRIDIN-2-YL)BUTAN-1-ONE Structure

22971-32-0

1-(PYRIDIN-2-YL...

~%

2-Acetopyridine Structure

1122-62-9

2-Acetopyridine

Cyclopropanol, 2-methyl-1-(2-pyridinyl)-, cis- (9CI) Structure

138835-96-8

Cyclopropanol, ...

1-Butanone,3-methyl-1-(2-pyridinyl)- Structure

6952-53-0

1-Butanone,3-me...

~%

2-Acetopyridine Structure

1122-62-9

2-Acetopyridine

N/A Structure

138835-93-5

N/A

(1s,3s)-3-methyl-1-(pyridin-2-yl)cyclobutan-1-ol Structure

138835-94-6

(1s,3s)-3-methy...

Detail
2-cyanopyridine Structure

100-70-9

2-cyanopyridine

~%

2-Acetopyridine Structure

1122-62-9

2-Acetopyridine


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