A Convenient Synthesis Of Phosphorus And Sulfonyl Substituted N-Imidazoles (Triazoles) Using The Corresponding Acid Chlorides And N-Trimethylsilyl Imidazoles ( …

W Dαbkowski, J Michalski…

Index: Dabkowski, W.; Michalski, J.; Skrzypczynski, Z. Phosphorus and Sulfur and the Related Elements, 1986 , vol. 26, p. 321 - 326

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Citation Number: 15

Abstract

Abstract The synthetic route phosphorus and sulfonyl-substituted N-imidazoles (triazoles) has been elaborated based on the method proposed by Birkofer8 et al. The appropriate compounds are obtained in high yield and of analytical purity by the action of N-trimethylsilyl imidazole (triazole) on the corresponding acid chlorides.

 Related Synthetic Route
2,4,6-Triisopropylbenzenesulfonyl chloride Structure

6553-96-4

2,4,6-Triisopro...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~98%

N-(2,4,6-Triisopropylbenzenesulfonyl)imidazole Structure

50257-40-4

N-(2,4,6-Triiso...

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1-trimethylsilyl-1,2,4-triazole Structure

18293-54-4

1-trimethylsily...

Tosyl chloride Structure

98-59-9

Tosyl chloride

~97%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(4-Methylphenylsulfonyl)-1,2,4-triazole Structure

13578-51-3

1-(4-Methylphen...

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N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

Tosyl chloride Structure

98-59-9

Tosyl chloride

~99%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(P-Toluenesulfonyl)imidazole Structure

2232-08-8

1-(P-Toluenesul...

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DIETHYL CHLOROPHOSPHITE Structure

589-57-1

DIETHYL CHLOROP...

1-trimethylsilyl-1,2,4-triazole Structure

18293-54-4

1-trimethylsily...

~40%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

diethyl phosphorotriazolidite Structure

58673-12-4

diethyl phospho...

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N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-imidazole sulfonic acid Structure

21108-81-6

1-imidazole sul...

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Diethyl chlorophosphate Structure

814-49-3

Diethyl chlorop...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(Diethoxyphosphinyl)imidazole Structure

16913-98-7

1-(Diethoxyphos...

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Diethyl chlorothiophosphate Structure

2524-04-1

Diethyl chlorot...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

O,O-diethyl 1H-imidazol-1-ylphosphonothioate Structure

107313-21-3

O,O-diethyl 1H-...

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Diisopropl chlorophosphate Structure

2574-25-6

Diisopropl chlo...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(diisopropoxyphosphinyl)imidazole Structure

67711-52-8

1-(diisopropoxy...

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Methanesulfonyl chloride Structure

124-63-0

Methanesulfonyl...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

n-methanesulfonylimidazole Structure

40736-26-3

n-methanesulfon...

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Methanesulfonyl chloride Structure

124-63-0

Methanesulfonyl...

1-trimethylsilyl-1,2,4-triazole Structure

18293-54-4

1-trimethylsily...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(methylsulfonyl)-1H-1,2,4-triazole Structure

75668-13-2

1-(methylsulfon...

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Chlorodiphenylphosphine Structure

1079-66-9

Chlorodiphenylp...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(di-phenylphosphino)imidazole Structure

54877-59-7

1-(di-phenylpho...

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DIETHYL CHLOROPHOSPHITE Structure

589-57-1

DIETHYL CHLOROP...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

diethyl (1H-imidazol-1-yl)phosphonite Structure

76089-86-6

diethyl (1H-imi...

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2-[chloro(methoxy)phosphoryl]-2-methylpropane Structure

34250-35-6

2-[chloro(metho...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

N/A Structure

97730-03-5

N/A

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Chloro(tert-butyl)phenylphosphine Structure

29949-69-7

Chloro(tert-but...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(tert-butyl(phenyl)phosphanyl)-1H-imidazole Structure

84674-91-9

1-(tert-butyl(p...

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N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

Tosyl chloride Structure

98-59-9

Tosyl chloride

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(P-Toluenesulfonyl)imidazole Structure

2232-08-8

1-(P-Toluenesul...

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N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

Diphenylphosphinic Chloride Structure

1499-21-4

Diphenylphosphi...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(diphenylphosphinoyl)imidazole Structure

71638-08-9

1-(diphenylphos...

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1-trimethylsilyl-1,2,4-triazole Structure

18293-54-4

1-trimethylsily...

Tosyl chloride Structure

98-59-9

Tosyl chloride

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-(4-Methylphenylsulfonyl)-1,2,4-triazole Structure

13578-51-3

1-(4-Methylphen...

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DIETHYL CHLOROPHOSPHITE Structure

589-57-1

DIETHYL CHLOROP...

1-trimethylsilyl-1,2,4-triazole Structure

18293-54-4

1-trimethylsily...

~0%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

diethyl phosphorotriazolidite Structure

58673-12-4

diethyl phospho...

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Methanesulfonyl chloride Structure

124-63-0

Methanesulfonyl...

N-(Trimethylsilyl)imidazole Structure

18156-74-6

N-(Trimethylsil...

~91%

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

n-methanesulfonylimidazole Structure

40736-26-3

n-methanesulfon...

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