Journal of the American Chemical Society 2002-07-31

High-performance, solution-processed organic thin film transistors from a novel pentacene precursor.

Ali Afzali, Christos D Dimitrakopoulos, Tricia L Breen

Index: J. Am. Chem. Soc. 124 , 8812-8813, (2002)

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Abstract

The Lewis acid-catalyzed Diels-Alder reaction of the organic semiconductor pentacene with N-sulfinylacetamide yields a soluble adduct. Spin-coated thin films of this adduct undergo solid-phase conversion to form thin films of pentacene at moderate temperatures. Organic thin film transistors fabricated by spin-coating this adduct, followed by thermal conversion to pentacene, exhibit the highest mobility reported to date for a solution-processed organic semiconductor.