Carbohydrate Research 2001-05-18

LiBF4-mediated C-glycosylation of glycals with allyltrimethylsilane: a facile synthesis of allyl C-glycosylic compounds.

J S Yadav, B V Reddy, L Chandraiah, K S Reddy

Index: Carbohydr. Res. 332(2) , 221-4, (2001)

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Abstract

The treatment of glycals with allyltrimethylsilane in the presence of lithium tetrafluoroborate in acetonitrile gave the corresponding allyl 2,3-unsaturated C-glycosylic compounds in excellent yields with high anomeric selectivity.