Organic & Biomolecular Chemistry 2007-06-21

Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.

Lutz Ackermann, Ludwig T Kaspar, Andreas Althammer

Index: Org. Biomol. Chem. 5(12) , 1975-8, (2007)

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Abstract

Two distinct economical catalysts for intramolecular hydroaminations of electronically unactivated alkenes with basic amines are described, which are based on (a) group 4 metal halides under basic reaction conditions or (b) Brønsted-acid organocatalysts.

Structure	Name/CAS No.	Molecular Formula	Articles
	Hafnium(IV) chloride CAS:13499-05-3	Cl₄Hf
	Zirconium(2+) chloride (1:2) CAS:10026-11-6	Cl₄Zr

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Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.

Abstract

Related Compounds