Tetrahedron

Hydrogenation of BF 2 complexes with 1, 3-dicarbonyl ligands

B Štefane, S Polanc

Index: Stefane, Bogdan; Polanc, Slovenko Tetrahedron, 2009 , vol. 65, # 11 p. 2339 - 2343

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Citation Number: 3

Abstract

The catalytic hydrogenation (H2, Pd/C) of a set of BF2 complexes with a 1, 3-dicarbonyl structural unit leading to monocarbonyl compounds has been studied. The transformation presented is general for the aryl-substituted derivatives and occurs under mild conditions (H2, 1bar, 25° C) in methanol or THF.

~90%

~91%

~85%

~82%

~99%

~82%

~66%

~87%

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