Tetrahedron

A modified palladium catalysed reductive amination procedure

…, G D'Anniballe, N Di Bello, G Nano, L Nicolini, A Topai…

Index: Berdini, Valerio; Cesta, Maria C; Curti, Roberto; D'Anniballe, Gaetano; Bello, Nicoletta Di; Nano, Giuseppe; Nicolini, Luca; Topai, Alessandra; Allegretti, Marcello Tetrahedron, 2002 , vol. 58, # 28 p. 5669 - 5674

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Citation Number: 39

Abstract

New, extended applications of a modified palladium catalysed reductive amination procedure are described; a mechanistic hypothesis alternative to the common imine pathway is proposed. This versatile method advances the usual reductive amination processes in terms of yield and shows high stereoselectivity whether applied to constrained carbonyl compounds.