Transformation of. alpha.-and. beta.-ionones into. alpha.-and. beta.-damascone and. beta.-damascenone using allylsilane chemistry

E Azzari, C Faggi, N Gelsomini…

Index: Journal of Organic Chemistry, , vol. 55, # 3 p. 1106 - 1108

Full Text: HTML

Citation Number: 12

Abstract

... 9, 124287-43-0; 10, 124287-44-1; 11, 124438-93-3; CH2= Transformation of CY- and P-Ionones into CY- and P-Damascone and 8-Damascenone Using Allylsilane Chemistry ... Page 3. 1108 J. Org. Chem. ... The organic layer was separated, washed with brine, and dried (NazS04). ...

 Related Synthetic Route
β-IONOL Structure

22029-76-1

β-IONOL

~%

Damascone Structure

23726-91-2

Damascone

(E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-yl acetate Structure

53319-91-8

(E)-4-(2,6,6-tr...

~%

Damascone Structure

23726-91-2

Damascone

(E)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)-3-(trimethylsilyl)but-1-ene Structure

127724-39-4

(E)-1-(2,6,6-tr...

~%

Damascone Structure

23726-91-2

Damascone

β-IONOL Structure

22029-76-1

β-IONOL

~%

1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIEN-1-YL)BUT-2-EN-1-ONE Structure

23726-93-4

1-(2,6,6-TRIMET...

(E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-yl acetate Structure

53319-91-8

(E)-4-(2,6,6-tr...

~%

1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIEN-1-YL)BUT-2-EN-1-ONE Structure

23726-93-4

1-(2,6,6-TRIMET...

(E)-2,6,6-Trimethyl-α-(1-propenyl)-1-cyclohexene-1-methanol Structure

35122-36-2

(E)-2,6,6-Trime...

~%

1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIEN-1-YL)BUT-2-EN-1-ONE Structure

23726-93-4

1-(2,6,6-TRIMET...

(E)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)-3-(trimethylsilyl)but-1-ene Structure

127724-39-4

(E)-1-(2,6,6-tr...

~%

1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIEN-1-YL)BUT-2-EN-1-ONE Structure

23726-93-4

1-(2,6,6-TRIMET...

Damascone Structure

23726-91-2

Damascone

~%

1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIEN-1-YL)BUT-2-EN-1-ONE Structure

23726-93-4

1-(2,6,6-TRIMET...


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