Dalton Transactions (Print Edition) 2014-11-28

Lattice water molecules tuned spin-crossover for an iron(II) complex with thermal hysteresis.

Yang-Hui Luo, Li-Jing Yang, Qing-Ling Liu, Yang Ling, Wei Wang, Bai-Wang Sun

Index: Dalton Trans. 43(44) , 16937-42, (2014)

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Abstract

A new iron(II) complex based on the 4,4'-dimethyl-2,2'-bipyridine ligand [Fe(4,4'-dmbpy)3(ClO4)(SCN)·3H2O (1·3H2O)] has been prepared and characterized. Structural studies and Hirshfeld surface analysis for complex 1·3H2O at three different temperatures (300, 240 and 130 K) are described. The UV-vis absorption spectrum of a water-free sample (1) in methanol solution and magnetic susceptibility measurements for solid-state samples 1·3H2O and 1 revealed that the removal of lattice water molecules from complex 1·3H2O changed the magnetic properties from the low-spin state (1·3H2O) to the complete spin-crossover (1) between 350-220 K with a thermal hysteresis of 7 K, and was accompanied by a colour change from brown to red.