Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2009-10-01

Unusual spectral shifts on fast violet-B and benzanilide: Effect of solvents, pH and beta-cyclodextin.

A Antony Muthu Prabhu, R K Sankaranarayanan, S Siva, N Rajendiran

Index: Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 74(2) , 484-97, (2009)

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Abstract

The absorption and fluorescence spectra of fast violet-B (FVB) and benzanilide (BA) have been analysed in different solvents, pH and beta-cyclodextrin. The inclusion complex of FVB with beta-CD is investigated by UV-visible, fluorimetry, AM 1, FTIR and SEM. The absorption maximum of FVB (anilino substitution) is red shifted than that of BA, but the benzoyl substitution hardly changed the ground state structure of BA. Compared to BA, the emission maxima of FVB largely blue shifted in cyclohexane and aprotic solvents, but red shifted in protic solvents and the longer wavelength maxima in FVB is due to the intramolecular charge transfer (TICT). In BA, the normal emission originates from a locally excited state and the longer wavelength band due to intramolecular proton transfer in non-polar/aprotic solvents and in protic solvents it is due to TICT state. beta-CD studies reveal that, FVB forms 1:2 complex from 1:1 complex and BA forms 1:2 complex with beta-CD.