Tetrahedron letters

Michael type addition of halides to alkynyl (phenyl) iodonium tetrafluoroborates. Stereoselective synthesis of (Z)-β-halovinyl (phenyl) iodonium halides

…, K Uemura, K Oshima, Y Masaki, M Kunishima, S Tani

Index: Ochiai, Masahito; Uemura, Koji; Oshima, Kunio; Masaki, Yukio; Kunishima, Munetaka; Tani, Shohei Tetrahedron Letters, 1991 , vol. 32, # 36 p. 4753 - 4756

Full Text: HTML

Citation Number: 26

Abstract

Abstract Michael type addition of halide ions (Cl− and Br−) to alkynyl (phenyl)-iodonium tetrafluoroborates (1) under acidic conditions proceeds in a completely stereoselective manner and affords (Z)-β-halovinyl (phenyl) iodonium halides (2), potential progenitors for generating α-haloalkylidenecarbenes, in high yields.