Nickel-catalyzed hydrodehalogenation of aryl halides

M Weidauer, E Irran, CI Someya, M Haberberger…

Index: Weidauer, Maik; Irran, Elisabeth; Someya, Chika I.; Haberberger, Michael; Enthaler, Stephan Journal of Organometallic Chemistry, 2013 , vol. 729, p. 53 - 59

Full Text: HTML

Citation Number: 16

Abstract

In the present study, the nickel-catalyzed dehalogenation of aryl and alkyl halides with iso- propyl zinc bromide or tert-butylmagnesium chloride has been examined in detail. With a straightforward nickel complex as pre-catalyst good to excellent yields and chemoselectivities were feasible for a variety of aryl and alkyl halides.