The Journal of Organic Chemistry

Reaction of 2-aryl-3-(N, N-dimethylamino)-1-propenes and their corresponding quaternary ammonium salts with organometallic species and reducing agents

JT Gupton, WJ Layman

Index: Gupton, John T.; Layman, William J. Journal of Organic Chemistry, 1987 , vol. 52, # 16 p. 3683 - 3686

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Citation Number: 27

Abstract

1 2 bp,”* C entry XR or R, M% vield (mess.. mm) 2a 4-MeOPh t-Bu Li 91 (61) l 72-76 (0.5) 2b 4-MeOPh n-Bu Li 75 (44)'72-76 (0.5) 2c 4-MeOPh Me MgBr b 2d 4-MeOPh Me MgBr b, c 2e 4-MeOPh (nB & CuLi 33 (22)'72-76 (0.5) a All compounds were purified by distillation or recrystallization and were found to be greater than 95% pure as determined by GLC analysis on a Shimadzu GC 7A gas chromatograph with a in. X 6 ft 3% SB-2401 column at ...