Journal of Agricultural and Food Chemistry 2001-06-01

Mobility and dissipation of ethofumesate and halofenozide in turfgrass and bare soil.

D S Gardner, B E Branham

Index: J. Agric. Food Chem. 49(6) , 2894-8, (2001)

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Abstract

The effect of turfgrass cover on the leaching and dissipation of ethofumesate and halofenozide was studied. Sampling cylinders (20 cm diam. x 30 cm long) were placed vertically in plots of creeping bentgrass (Agrostis palustris Huds.), tall fescue (Festuca arundinaceae Schreb.), or bare soil. ethofumesate [(+/-)-2-ethoxy-2,3-dihydro-3,3-dimethylbenzofuran-5-yl methansulfonate] was applied at 840 g ai ha(-)(1) on September 21, 1997. Halofenozide (N-4-chlorobenzoyl-N'-benzoyl-N'-tert-butylhydrazine) was applied at 1680 g ai ha(-)(1) on August 30, 1998. Replicate sampling cylinders were removed 2 h after treatment and 4, 8, 16, 32, and 64 days after treatment. Sampling cylinders were sectioned by depths and soil extracts were assayed by HPLC with a pesticide detection limit of 0.01 mg kg(-)(1). Turfgrass was divided into verdure and thatch and analyzed separately. ethofumesate leaching in turfgrass was reduced by at least 95% compared to leaching in bare soil. The half-life of ethofumesate in bare soil was 51 days compared to 3 days in turfgrass. Halofenozide showed similar leaching with or without turfgrass. Fifty percent dissipation of halofenozide did not occur within 64 days, regardless of organic matter cover.