Tetrahedron

Dienediolates of unsaturated carboxylic acids in synthesis. Synthesis of cyclohexenones and polycyclic ketones by tandem Michael-Dieckmann decarboxylative …

MJ Aurell, P Gaviña, R Mestres

Index: Aurell, Maria J.; Gavina, Pablo; Mestres, Ramon Tetrahedron, 1994 , vol. 50, # 8 p. 2571 - 2582

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Citation Number: 17

Abstract

Substituted 2-cyclohexenones 4 to 7 and hexaxydronaphthalenones and hexahydroindenones 13 to 18 are prepared by tandem Michael-Dieckmann addition of lithium dienediolates of acyclic and alicyclic unsaturated carboxylic acids to the lithium salts of the same or other unsaturated carboxylic acids.

~32%

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