Journal of Organic Chemistry 2000-11-01

Palladium-catalyzed cross-coupling of 3-iodobut-3-enoic acid with organometallic reagents. Synthesis Of 3-substituted but-3-enoic acids

Abarbri, Parrain, Kitamura, Noyori, Duchene

Index: J. Org. Chem. 65 , 7475, (2000)

Full Text: HTML

Abstract

3-Substituted but-3-enoic acids were obtained in good yields under mild experimental conditions by palladium-catalyzed cross-coupling of 3-iodobut-3-enoic acid with organozinc or organotin compounds using PdCl(2)(MeCN)(2) as catalyst and DMF as solvent.

Structure	Name/CAS No.	Molecular Formula	Articles
	Acetonitrile-dichloropalladium (2:1) CAS:14592-56-4	C₄H₆Cl₂N₂Pd

[Synthesis , 803, (1992)]

[Tetrahedron 63 , 2123, (2007)]

Stille, J. K.; Groh, L.
[J. Am. Chem. Soc. 109 , 813, (1987)]

Hosokawa, T.; Takano, M.; et al.
[Tetrahedron Lett. 33 , 6643, (1992)]

Mori, H.; Kubo, H.; et al.
[Tetrahedron Lett. 38 , 5311, (1997)]

Palladium-catalyzed cross-coupling of 3-iodobut-3-enoic acid with organometallic reagents. Synthesis Of 3-substituted but-3-enoic acids

Abstract

Related Compounds