Journal of the American Chemical Society 2009-09-16

A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

Shunsuke Chiba, Yan-Jun Xu, Yi-Feng Wang

Index: J. Am. Chem. Soc. 131 , 12886, (2009)

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Abstract

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.